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Potential Surface for the Quadruply Degenerate Rearrangement of Bicyclo[3.1.0]hex-2-ene

โœ Scribed by Suhrada, Christopher P.; Houk, K. N.


Book ID
125981318
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
114 KB
Volume
124
Category
Article
ISSN
0002-7863

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โœ Albert Padwa; Thomas J. Blacklock; Roman Loza ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 187 KB

The triplet sensitized irradiation of 3-allyl-diaryl-substituted cyclopropenes to m.l.O]hex-2-enes proceeds via an intramolecular [2+2]-cycloaddition followed by a subsequent rearrangement of the initially formed tricycl0[2.2.0.0~~~]hexane skeleton. Previous work from this laboratory has shown that