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Potential scan voltammetry with finite diffusion. Unified theory

✍ Scribed by Keller, H. E.; Reinmuth, W. H.

Book ID
120883409
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
904 KB
Volume
44
Category
Article
ISSN
0003-2700

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Staircase voltammetry with finite diffus
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✍ Milivoj LovriΔ‡; Ε bojka Komorsky-LovriΔ‡; Fritz Scholz πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 295 KB

A theory of the staircase voltammetry in a thin-layer cell is developed. The influence of the cell thickness and the redox reaction rate constant on the current and the peak potentials is analyzed. For moderately thick cells, the kinetic maximum is predicted. The relationship between peak currents a