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Potential positive electrodes for high-voltage magnesium-ion batteries

✍ Scribed by Ichitsubo, Tetsu; Adachi, Takero; Yagi, Shunsuke; Doi, Takayuki

Book ID
118008733
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
845 KB
Volume
21
Category
Article
ISSN
0959-9428

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MnVzO,, (0.5 < 6 < 1) amorphous oxides reversibly insert large amounts of Li (e.g. Li12MnV206,96) at low voltage (= 1 V). During the first Li insertion, Mn 4+ is first reduced to Mnz+ and Vs' is reduced to V3+. Upon further cycling, the V oxidation state varies reversibly between +3 and +5, whereas