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Potential Field and Force Constants of B3O3(O−)3

✍ Scribed by G. Nagarajan

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
291 KB
Volume
71
Category
Article
ISSN
0037-9646

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✦ Synopsis

Abstract

For the evaluation of potential constants for the nonplanar vibrations of B~3~O~3~(O^−^)~3~ which possesses a cyclic structure with the symmetry point group D~3h~, the Wilson's group theoretical method has been applied. An orthonormalized set of symmetry coordinates satisfying the transformation properties has been constructed. The secular equations obtained with the help of F and G matrices have been solved to obtain two major and three interaction constants. The interaction constants are not found to be much significant.

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