𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Potential energy curves for the X0+ and A0+ states of BiF

✍ Scribed by A.J. Ross; R. Bacis; J. D'Incan; C. Effantin; B. Koffend; A. Topouzkhanian; J. Vergès

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
541 KB
Volume
166
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

From a low-resolution spectrum of the AO+ -+X0+ emission of BiF, in which bandheads were clearly visible but the rotational structure remained unresolved, we have extended the potential energy curves for the X and A states up to v= 36 and 25 respectively. From intensity data, we observe the pattern of populations produced in the vibrational levels of the AO* state by the reaction of bismuth vapour with F2. We estimate a well depth for the ground state of 40000 cm-', almost twice the current ab inirio value.

📜 SIMILAR VOLUMES

Analytical potential curves for the X 1Σ
Analytical potential curves for the X 1Σ+ and 0+ states of NaI
✍ J. Wang; A.J. Blake; D.G. McCoy; L. Torop 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 511 KB

The potentials for the X '2' and O+ states of NaI are determined in analytical form by a numerical optimization procedure. The accuracy of the optimum potentials is demonstrated by direct comparison of the calculated term energies and rotational constants with the measured values, as well as by asse

Potential energy curves for the ground a
Potential energy curves for the ground and excited states of alh+
✍ Martyn F. Guest; David M. Hirst 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 394 KB

PotentA energy curves for low-lying doublet states of AlH+ dlssociatmg to Ai+ + H, Al+(3P) f H, Ai+ f Hand Al(\*P) + H+ have been detemuned by ab mitt0 confiiatton interaction calculations. Tbe B' \*E+ state is predicted to be bound with a bond length of 2.06 A. Shallow muum are found for 4 \*Z+ and