An 12 vapor ceII and an optical multichannel analyzer allowed the simultaneous detection (from -60 to +60 cm-') of inelastic scattering from a Ag electrode (electrochemicalIy roughened in 0.1 M KI). Separation of the low-frequency mode, which peaks at =7 cm-', from the inelastic continuum, which inc
โฆ LIBER โฆ
Potential-dependent measurements of the low-frequency mode, the inelastic continuum, elastic scattering and sers from a Ag electrode
โ Scribed by Kevin F. Wall; Marcia L.A. Temperini; Richard K. Chang
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 487 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
An I2 vapor absorption filter attenuated the elastically scattered light and allowed the separation of the low-frequency mode from the large inelastic continuum signal near 0 cm-'. The potential dependence of the low-frequency mode, the inelastic continuum, the SERS of adsorbates, and the elastic scattering was measured from a Ag electrode. All the inelastic scattering contributions have similar potential dependences while the elastic scattering does not.
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