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Potassium Organotrifluoroborates: New Partners in Palladium-Catalysed Cross-Coupling Reactions

✍ Scribed by Sylvain Darses; Guillaume Michaud; Jean-Pierre Genêt

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 349 KB
Volume: 1999
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(199908)1999:8<1875::aid-ejoc1875>3.0.co;2-w

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✦ Synopsis

The preparation of various potassium organotrifluoroborates partners in palladium-catalysed cross-coupling reactions with arenediazonium salts, affording biaryl and styrene bearing either aryl, alkenyl, or alkynyl substituents is described. These stable salts are shown to be very efficient derivatives in high yields.

of a wide variety of potassium organotrifluoroborates and [a]

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