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Potassium Organotrifluoroborates in Rhodium-Catalyzed Asymmetric 1,4-Additions to Enones

✍ Scribed by Mathieu Pucheault; Sylvain Darses; Jean-Pierre Genêt


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
179 KB
Volume
2002
Category
Article
ISSN
1434-193X

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✍ Fang Luo; Shen Pan; Changduo Pan; Pengcheng Qian; Jiang Cheng 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB 👁 1 views

An efficient rhodium-catalyzed lactonization of phthalaldehyde with potassium organotrifluoroborates to access 3-arylphthalides has been developed. Moreover, palladium is a also good catalyst for such transformation.