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Potassium ion responsive coated wire electrode based on valinomycin

โœ Scribed by Cattrall, R. W.; Tribuzio, S.; Freiser, Henry.

Book ID
125844339
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
258 KB
Volume
46
Category
Article
ISSN
0003-2700

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Mechanistic aspects of the K+ ion select
Mechanistic aspects of the K+ ion selective electrode based on valinomycin-PVC
โœ R.D. Armstrong ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 355 KB

The mechanism of ion selective electrode membranes based on valinomycin+KBPh, in plasticized PVC is discussed in the light of recent impedance studies. In a typical membrane the K + is largely present as K+val -BPh, ion pairs. The transport number for K+val is -0.87 whilst that for BPh4 is -0.13. At