Potassium bis(μ-sulfato-1κO:2κO′)bis[cis-dioxido-cis-bis(sulfato-κO)tungstate(VI)]
✍ Scribed by Schäffer, Susan J. Cline ;Berg, Rolf W.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 349 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
bis[aqua-(l-sulfato-j 3 O,O 0 0 0 :O 0 0 00 0 0 )(l-sulfato-j 4 O,O 0 0 0 :O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 )-(sulfato-jO)terbate(III)] tetrahydrate]
The reaction of ferric sulfate with ethylenediamine in the presence of acid under hydrothermal conditions results in the title compound, (C 2 H 10 N 2 ) 2 [Fe III (OH)(SO 4 ) 2 ](SO 4 )ÁH 2 O. The six-coordinate ferrate dianion participates in a 2 -hydroxo-di-2 -sulfate-bridged chain. The component
Bis[l 2 -bis(salicylidene)propane-1,3-diaminatoj 4 O,N,N 0 0 0 ,O 0 0 0 :j 2 O,O 0 0 0 ]bis(l 2 -nitrato-jO:jO 0 0 0 )tricopper(II)
Single-crystal X-ray study T = 291 K Mean (C-C) = 0.003 A R factor = 0.025 wR factor = 0.069 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.