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Potassium-39 NMR study of the complexation kinetics of potassium(+) ion by 18-crown-6 in some nonaqueous solvents

✍ Scribed by Schmidt, Emmanuel; Popov, Alexander I.


Book ID
126840619
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
726 KB
Volume
105
Category
Article
ISSN
0002-7863

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## Abstract ^39^K NMR spectroscopy was used to study a blue potassium solution in tetraglyme containing 18‐crown‐6 and in a solution without the crown ether. Direct proof of the existence of potassium anions and complexed potassium cations in both solutions has been presented.

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## Abstract Blue potassium solution in THF containing 18‐crown‐6 was investigated by means of ^39^K NMR spectroscopy. The presence of potassium anions and complexed potassium cations was demonstrated. Spin‐lattice and spin‐spin relaxation times were measured in the temperature range 176–295 K. An a