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Post-Synthesis Functionalization of (Meth)acrylate Based Monoliths via Electron Beam Triggered Graft Polymerization

✍ Scribed by Matthias J. Beier; Wolfgang Knolle; Andrea Prager-Duschke; Michael R. Buchmeiser

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 174 KB
Volume: 29
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.200800153

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✦ Synopsis

Abstract

Porous polymeric monoliths were prepared via electron beam triggered free radical polymerization of (meth)acrylates. Post‐synthesis functionalization of these supports was accomplished via electron beam initiated free radical graft polymerization of methacryloyl‐substituted NHC precursors. The grafted precursors were converted into the corresponding copper complexes. Cu‐loadings were between 1.3 mg · g^−1^ and 1.5 mg · g^−1^. These supported catalysts were used in selected CO hydrosilylation and cyanosilylation reactions using a continuous flow setup.

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✍ Rajendar Bandari; Wolfgang Knolle; Andrea Prager-Duschke; Michael R. Buchmeiser 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 192 KB

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