Post-polymerization of methyl methacrylate after electroinitiation at the anode
β Scribed by Palit, Santi R.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 330 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0449-2994
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The bulk polymerization of MMA at high temperature (120 -180Β°C) in a continuous pilot-plant reactor has been studied. The polymerization is initiated by diterbutyle peroxide and the chain transfer agent is 1-butanethiol. A simulation program has been developed to predict the steady state behavior of
Chain transfer involving thiourea in radical polymerization of methyl methacrylate in acidic aqueous media has been studied by polymer endgroup analysis using the dye-partition technique. Thiourea has feeble reactivity in chain transfer, the transfer constant with respect to poly (methyl methacrylat
## Abstract Polystyreneβ__block__βpoly(methyl methacrylate) (PSβ__b__βPMMA) has been synthesized by sequential anionic and reverse atom transfer radical polymerization (ATRP) or a variation of nitroxide mediated polymerization (NMP) from a single initiating site, specifically the 9βcarbon on 2,7βdi