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Possible mechanism for the reduction of transition metals by tetrahydroborate: Co(I) and Ni(I) intermediate complexes

✍ Scribed by D.G. Holah; A.N. Hughes; B.C. Hui


Publisher
Elsevier Science
Year
1974
Weight
94 KB
Volume
10
Category
Article
ISSN
0020-1650

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## Abstract Transition metal cations Co^2+^, Ni^2+^ and Zn^2+^ form 1 : 1 : 1 ternary complexes with 2,2′‐bipyridine (bpy) and peptides in aqueous methanol solutions that have been studied for tripeptides GGG and GGL. Electrospray ionization of these solutions produced singly charged [Metal(bpy)(pe