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"Positronic" effective charges of anions in polar substances

✍ Scribed by E. P. Prokop’ev

Book ID
118293793
Publisher
Springer
Year
1997
Tongue
English
Weight
338 KB
Volume
40
Category
Article
ISSN
1573-9228

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Substituent-induced polarization of char
Substituent-induced polarization of charge in phenalenyl anions
✍ Joost T. M. van Dijk; Steven A. Steggerda; Johan Lugtenburg; Jan Cornelisse 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 119 KB

The effect of trimethylsilyl, alkynyl and cyano substituents on the charge distribution of the phenalenyl anionic nucleus was examined using semiempirical calculations and NMR spectroscopy. With these techniques it was demonstrated that the trimethylsilyl and cyano substituents are capable of attrac