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Positron annihilation studies in solid lanthanide trisacetylacetonates

✍ Scribed by A. Marques-Netto; S.M.C. Maximobicalho; J.C. Machado; E.O. Fantine; J.Ch. Abbé; G. Duplâtre


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
252 KB
Volume
141
Category
Article
ISSN
0009-2614

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✦ Synopsis


Positron annihilation lifetimes and Doppler-broadened annihilation lines have been measured in solid Ln(aa),, where Ln = La, Sm, Eu, Gd, Dy, Ho, Er, Tm and aa=CH,COCHCOCHx. The results point to the formation of positronium in all complexes except that of europium. This result is attributed to a charge-transfer process ligand+metal in the europium compound and metal-tligand in the others,


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A computational technique is developed to evaluate positron distribution as well as the electron-positron momentum densities in diamond and the use of these provide us the means of interpreting the k-space densities obtained experimentally using the two-dimensional angular correlation of annihilatio