A novel strapped porphyrin receptor Zn1, in which two electron-rich bis(p-phenylene)-34-crown ether-10 units are incorporated, has been designed and synthesized from the newly developed intermediate 7 for investigating new chemistry of molecular recognition. 1 H NMR and UV -Vis studies revealed that
Porphyrin phosphonates: novel anionic receptors for saccharide recognition
✍ Scribed by Vladimı́r Král; Oleksandr Rusin; Jana Charvátová; Pavel Anzenbacher Jr.; Jaroslav Fogl
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 99 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Novel porphyrin phosphonates (1-3) exhibit binding of alkyl pyranosides in organic media (receptor 1), monosaccharides, selected disaccharides in water (receptors 2 and 3); effective binding for D(-) fructose, D(+) maltose and a-D-lactose were found; association constants for 1 (in acetonitrile) and for 2 and 3 (in water) are of the order 10 4 M -1 .
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