Volume phase transitions of poly(N-isopropylacrylamide) (PNIPAM) latex particles in mixed water-N,N-dimethylformamide (DMF) solutions were studied at different temperatures and crosslink densities using dynamic light scattering. A collapse-swelling behaviour was observed on the addition of N,N-dimet
β¦ LIBER β¦
Porous poly(N-isopropylacrylamide) gels polymerized in mixed solvents of water andN,N-dimethylformamide
β Scribed by Hideaki Tokuyama; Noriaki Ishihara; Shuji Sakohara
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 726 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0170-0839
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The macroscopic volume shrinkage and swelling of poly (N-isopropylacrylamide) (PNIPA) gel induced by the compositional change in the methanol-water mixed solvent is correlated to the change in the nanoscopic free volume size and numerical concentration formed in the PNIPA gels. The free volume size