In a previous study, a simple acid catalyzed reaction (esterification) was found to predict excellently conductivity of a membrane contaminated with NH 4 + or Na + . Since measurement of the conductivity of Nafion in a catalyst layer is problematic, being able to predict this conductivity for variou
Pore scale modeling of a proton exchange membrane fuel cell catalyst layer: Effects of water vapor and temperature
β Scribed by Kyle J. Lange; Pang-Chieh Sui; Ned Djilali
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 746 KB
- Volume
- 196
- Category
- Article
- ISSN
- 0378-7753
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β¦ Synopsis
A pore scale model of a polymer electrolyte membrane (PEM) fuel cell cathode catalyst layer is developed which accounts for species transport, electrochemical reactions and thermal transport. Effective transport parameters are computed over a range of operating conditions including the effective oxygen diffusivity, effective water vapor diffusivity, effective proton conductivity, effective electron conductivity and the effective thermal conductivity. In addition, the total amount of oxygen consumption is computed for different operating conditions. Finally, a critical assessment of the impact of assumptions made in the absence of detailed morphological data is presented.
π SIMILAR VOLUMES
A two-dimensional computational fluid dynamics model of a proton exchange membrane fuel cell (PEMFC) was formulated by taking into account the liquid water transport through the membrane electrode assembly (MEA) on the basis of the agglomerate catalyst framework. Various modes of water transport in
## Abstract This study investigates the gas permeability, conductivity and performance of two types of gas diffusion layer (90βgβm^β2^ and 190βgβm^β2^) with various hydrophobic treatments. The performance is measured using a single proton exchange membrane fuel cell (PEMFC) with an active area of 2