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Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-furan-2-carboxylato-κ2O:O′)cadmium(II)]

✍ Scribed by Chen, Man-Sheng ;Zhang, Chun-Hua ;Kuang, Dai-Zhi ;Feng, Yong-Lan ;Deng, Yi-Fang

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 148 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807016777

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✦ Synopsis

In the crystal structure of the title compound, [Cd(C 5 H 3 O 3 ) 2 -(C 10 H 8 N 2 )] n , which was synthesized from the reaction of Cd(ClO 4 ) 2 Á6H 2 O, furan-2-carboxylic acid and 4,4 0 -bipyridine in methanol-water, the Cd atom is octahedrally coordinated by two N atoms of two bipyridine ligands and four O atoms of four furan-2-carboxylate ligands. The carboxylate group coordinates in a bridging mode; the Cd atom and 4,4 0bipyridine ligand lie on a crystallographic twofold rotation axis. The compound exhibits a layer structure arising from the bonding modes of the furan-2-carboxylate anion and the 4,4 0bipyridine heterocycle.

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