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Polyvalent-metal salts of heteropolyacid as efficient heterogeneous catalysts for Friedel–Crafts acylation of arenes with carboxylic acids

✍ Scribed by Ken-ichi Shimizu; Kenjiro Niimi; Atsushi Satsuma


Book ID
119216184
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
114 KB
Volume
9
Category
Article
ISSN
1566-7367

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✍ Mona Hosseini Sarvari; Hashem Sharghi 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 82 KB

TsOH/graphite was found to be an effective catalyst system for the Friedel ± Crafts acylation of aromatic compounds with carboxylic acids. Both aliphatic and aromatic carboxylic acids reacted smoothly under TsOH/ graphite catalysis to afford the corresponding aromatic ketones in high yields. The gra