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Polythiosemicarbazides. I. Preparation and properties of the polymers and some simple metallic chelates

✍ Scribed by Campbell, Tod W. ;Tomic, Ernst A.

Publisher
John Wiley and Sons
Year
1962
Weight
415 KB
Volume
62
Category
Article
ISSN
0022-3832

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✦ Synopsis

Abstract

The condensation of N,N′‐diaminopiperazine with methylenebis(4‐phenyl isothiocyanate) proceeded easily in dimethyl sulfoxide solution to give a high molecular weight, soluble, polythiosemicarbazide (I).
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In agreement with the known behavior of monomeric thiosemicarbazides, the polymer reacted readily with various metal ions to give metallic chelates. These chelates did not have the expected thermal stability, however.

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