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Polystyrene with Pendant Mixed Functional Ruthenium(II)-Terpyridine Complexes

✍ Scribed by Marcel Heller; Ulrich S. Schubert

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
409 KB
Volume
23
Category
Article
ISSN
1022-1336

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## Abstract [2]Rotaxanes based on the 1,2‐bis(pyridinium)ethane⊂[24]crown‐8 ether motif were prepared that contain a terminal terpyridine group for coordination to a transition‐metal ion. These rotaxane ligands were utilized in the preparation of a series of heteroleptic [Ru(terpy)(terpy–rotaxane)]

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## Abstract (η^6^‐Arene)ruthenium(II) complexes of the type [{[η^6^‐C~6~H~5~(CH~2~)~n~COOH]Ru(µ‐Cl)Cl}~2~] (2a, n = 1; 3, n = 3) with tethered carboxylate groups can be obtained by dehydrogenation of the appropriate cyclohexadiene with RuCl~3~·3H~2~O. Formation of a κO‐coordinated chelate in weakly