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Polystyrene-Bound Dioxirane: a New Class of Recyclable Oxidising Reagent

✍ Scribed by Shiney, Abraham; Rajan, P. K.; Sreekumar, K.

Book ID
101228621
Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
431 KB
Volume
41
Category
Article
ISSN
0959-8103

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✦ Synopsis

Polystyrene-bound dioxirane containing a five-methylene spacer arm between the polymer matrix and reagent function has been prepared and investigated as a new class of recyclable oxidising reagent for various organic substrates. The new reagent was found to oxidise alkenes to epoxides, pyridines to N-oxides and amines to nitro compounds in near-quantitative yields. The spent reagent could be regenerated to the dioxirane resin by a simple reaction without considerable loss in reactivity.

K e y words: polystyrene-supported solid-phase analogue

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