𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Polypropylene degradation control during reactive extrusion

✍ Scribed by Sheng-Hong Pong; Chuan-Pin Lu; Ming-Chih Wang; Shih-Hsuan Chiu


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
175 KB
Volume
95
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

In this work, a proportional‐integral‐derivative (PID) control scheme with two different tuning methods to control the degree of degradation of polypropylene (PP) during reactive extrusion is proposed. The concentration of dicumyl peroxide is taken as the manipulated variable. The molten viscosity of PP under processing is taken as the controlled variable. The degree of degradation is determined by a viscosity function derived by an off‐line identification. A first‐order‐plus‐time‐delay empirical model is identified to simulate the system plant. Both Ziegler–Nichols tuned PID and internal model control (IMC)‐based PID controllers are implemented on the system. Better performances in settling time and precision can be achieved using the IMC‐based PID controller. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 280–289, 2005


📜 SIMILAR VOLUMES


Reactive extrusion of polypropylene II:
✍ D. Suwanda; R. Lew; S. T. Balke 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 667 KB

A kinetic model for the free-radical-initiated molecular weight degradation of polypropylene was further developed. The model has a single variable parameter, the initiator efficiency, f . Assumptions were detailed, new comparisons with experimental data presented, and model sensitivity to the value

In situ compatibilization of polypropyle
✍ Rongbo Li; Xiuqin Zhang; Lijuan Zhou; Jinyong Dong; Dujin Wang 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 311 KB 👁 2 views

## Abstract __In situ__ compatibilization of polypropylene (PP) and polystyrene (PS) was achieved by combinative application of tetraethyl thiuram disulfide (TETD) as degradation inhibitor and di‐__tert__‐butyl peroxide as degradation initiator in the process of reactive extrusion. The PP/PS blends