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Polyphenylquinoxalines containing pendant phenylethynyl groups: Preliminary mechanical properties

✍ Scribed by Paul M. Hergenrother


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
704 KB
Volume
28
Category
Article
ISSN
0021-8995

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✦ Synopsis


Polyphenylquinoxalines (PPQ's) containing various amounts of crosslinkable pendant phenylethynyl groups were prepared from the reaction of 3,3',4,4'-tetraaminodiphenyl ether, 4,4'-oxydibenzil, and 4,4'-oxybis(4"-phenylethynylbenzil). The distribution of the pendant phenylethynyl groups along the polymer chain was varied in an attempt to alter the properties of the polymers. Preliminary film, adhesive, and laminate properties of PPQ void of pendant crosslinkable groups and containing pendant phenylethynyl groups were determined. The thermally induced reaction of the phenylethynyl group crosslinked the polymer which resulted in better dimensional stability a t elevated temperatures.


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