Poly(arylene ether)s ( 3) containing pendant benzoyl groups were prepared by the aromatic substitution reaction of 2,5-difluoro-4-benzoylbenzophenone ( 2) with hydroquinone (1a) and methylhydroquinone (1b) in the presence of potassium carbonate in N,N-dimethylacetamide. The polycondensation proceede
Polyphenylquinoxalines containing pendant phenylethynyl groups: Preliminary mechanical properties
✍ Scribed by Paul M. Hergenrother
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 704 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
✦ Synopsis
Polyphenylquinoxalines (PPQ's) containing various amounts of crosslinkable pendant phenylethynyl groups were prepared from the reaction of 3,3',4,4'-tetraaminodiphenyl ether, 4,4'-oxydibenzil, and 4,4'-oxybis(4"-phenylethynylbenzil). The distribution of the pendant phenylethynyl groups along the polymer chain was varied in an attempt to alter the properties of the polymers. Preliminary film, adhesive, and laminate properties of PPQ void of pendant crosslinkable groups and containing pendant phenylethynyl groups were determined. The thermally induced reaction of the phenylethynyl group crosslinked the polymer which resulted in better dimensional stability a t elevated temperatures.
📜 SIMILAR VOLUMES
The gas transport of hydrogen, oxygen, nitrogen, carbon dioxide, and methane gases in a series of poly(aryl ether ketone)s was examined. These polymer membranes have a wide range of permeability coefficients and permselectivity coefficients, showing excellent gas-transport properties. The enhanced i
## Abstract A new photo‐functional copolymer was designed by etherification or esterification of poly‐[__N__‐(4‐hydroxyphenyl)maleimide‐__co__‐styrene] or poly[__N__‐(4‐carboxyphenyl)maleimide‐__co__‐styrene] with __p__‐bromomethylnitrobenzene using 1,8‐diazabicyclo[5.4.0]‐undec‐7‐ene (DBU) as the