## Abstract Poly[2‐(__tert__‐butoxycarbonyl)‐1,4‐phenylene] (2) was prepared by the Ni‐catalyzed polymerization of __tert__‐butyl 2,5‐dichlorobenzoate (1). The microstructure of polymer 2 was probably alternating head‐to‐head and tail‐to‐tail. This polymer was soluble in dipolar aprotic solvents, c
Poly(p-phenylene-diselenocarbonate) and poly(p-phenylene-diselenothiocarbonate): New semiconducting polymers
✍ Scribed by F.R. Dáaz; A. Godoy; L.H. Tagle; N. Valdebenito; J.C. Bernede
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 425 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
New polymers which contain selenium in the main chain have been synthesized. Poly(p-phenylene-diseelenocarbonate) and poly(p-phenylene-diseelenothiocarbonate)
have been studied by X-ray photoelectron spectroscopy (XPS). Electrical conductivity was measured on samples without dopant agent and on samples doped with AICl,, FeCl,, SbFs and 11. The morphology of these compounds was studied using a scanning electron microscope (SEM).
📜 SIMILAR VOLUMES
## Abstract The synthesis and properties of soluble, conjugated polymers consisting of oligo(__p__‐phenylene) sequences linked by ethylene, vinylene, or ethylene, units are reported. Benzene‐, stilbene‐, diphenylacetylene‐ and 1,2‐diphenylethane derivatives serve as monomers and are connected by th
Photon correlation spectroscopy in both polarized and depolarized geometry was employed to investigate the dynamics of a ribbon-type polymer exhibiting good solubility. In dilute solution, the translational diffusion for all examined molecular weights has confirmed the picture of wormlike chains wit