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Polynuclear croconato-bridged-copper(II) complexes derived from tri- and tetra-dentate amines

✍ Scribed by Salah S. Massoud; Ramon Vicente; Patricia R. Fontenot; August A. Gallo; Masahiro Mikuriya; Jörg H. Albering; Franz A. Mautner


Book ID
116843476
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
727 KB
Volume
46
Category
Article
ISSN
0277-5387

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μ-1,3- (trans) and μ-1,2- (cis) Bonding
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## Abstract A novel series of dinuclear squarato‐bridged copper(II) and nickel(II) complexes [Cu~2~(TPA)~2~(μ~1,3~‐C~4~O~4~)](ClO~4~)~2~·4H~2~O (1), [Cu~2~(MeDPA)~2~(μ~1,3~‐C~4~O~4~)(H~2~O)~4~](ClO~4~)~2~ (2) and [Ni~2~(TPA)~2~(μ~1,2~‐C~4~O~4~)(H~2~O)~2~](ClO~4~)~2~ (3) [C~4~O~4~^2–^ = dianion of 3