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Polynuclear Complexes of Copper(I) and the 2-(3(5)-Pyrazolyl)-6-methylpyridine Ligand: Structures and Reactivity toward Small Molecules

✍ Scribed by Singh, Kuljeet; Long, Jeffrey R.; Stavropoulos, Pericles


Book ID
126162899
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
144 KB
Volume
37
Category
Article
ISSN
0020-1669

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The organorhodium(I) complexes [Rh(PNP)R] [PNP = 2,6-stable monohydridorhodium(III) complex [Rh(PNP)ClH-(CH 3 CN)]SO 3 CF 3 (7) was obtained by the reaction of bis(diphenylphosphanylmethyl)pyridine, R = CH 3 (3a), C 6 H 5 (3b)] were synthesized from [Rh(PNP)(C 2 H 4 )]BF 4 (1a) and LiR [Rh(PNP)Cl] w