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Polymorphous phase transition in the clathrate [Cd(py)4(NO3)2]·2py at 221 K

✍ Scribed by Boris A. Kolesov; Dmitriy V. Soldatov; Yuri A. Dyadin


Book ID
111729885
Publisher
Royal Society of Chemistry
Year
1996
Tongue
English
Weight
115 KB
Volume
6
Category
Article
ISSN
0959-9436

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Structure of cobalt doped K2Cd2(SO4)3lan
✍ M. J. L. Percival; W. W. Schmahl; E. Salje 📂 Article 📅 1989 🏛 Springer-Verlag 🌐 English ⚖ 700 KB

X-ray structure determinations of Langbeinite type K2(Cda-xCox)2(SO4)3, x = 0.02 at three temperatures (440, 540 and 640 K) above the P213-P212121 transition temperature (434 K) reveal that the M 2+ (M2+=Cd) ion is displaced from the centre of the octahedron at all temperatures in the cubic phase. S