The thermodynamic relationships between the two known polymorphs of paracetamol have been investigated, and the subsequent pressure-temperature and temperature-volume phase diagrams were constructed using data from crystallographic and calorimetric measurements as a function of the temperature. Irre
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Polymorphism of progesterone: Relative stabilities of the orthorhombic phases I and II inferred from topological and experimental pressure-temperature phase diagrams
✍ Scribed by Maria Barrio; Philippe Espeau; Josep Lluis Tamarit; Marc-Antoine Perrin; Nestor Veglio; René Ceolin
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 358 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0022-3549
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The melt from the usual monoclinic phase (Phase I) of biclotymol (T(fusI) = 400.5 +/- 1.0 K, Delta(fus)H(I) = 36.6 +/- 0.9 kJ mol(-1)) recrystallizes into another phase, Phase II, that melts at T(fusII) = 373.8 +/- 0.2 K (Delta(fus)H(II) = 28.8 +/- 1.0 kJ mol(-1)). The transformation of Phase II int