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Polymorphism in NaSbO3: Structure and Bonding in Metal Oxides.

โœ Scribed by Hiroshi Mizoguchi; Patrick M. Woodward; Song-Ho Byeon; John B. Parise


Publisher
John Wiley and Sons
Year
2004
Weight
59 KB
Volume
35
Category
Article
ISSN
0931-7597

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Structure and bonding in metal sulfoxide
โœ Mario Calligaris ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 421 KB

Average S-O bond distances were calculated, from accurate X-ray data, for free and coordinated sulfoxides, showing a decrease from free sulfoxides (avearge 1.492(1) ร…) to S-bonded metal complexes (average 1.4738(7) ร…). On the contrary, the S-O bond distance increases in H-bonded uncoordinated sulfox