## Abstract Syndiotactic polystyrene (sPS) nanorods with different diameters have been prepared by using anodic aluminum oxide templates, and the orientation of the sPS crystals in the nanorods has been investigated by FT‐IR spectroscopy. It is found that the __c__ axis of the __β__′ crystals prefe
Polymorphic Behavior of Syndiotactic Polystyrene Crystallized in Cylindrical Nanopores
✍ Scribed by Wu, Hui; Wang, Wei; Huang, Yan; Wang, Cheng; Su, Zhaohui
- Book ID
- 127060121
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 82 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The complex polymorphic behavior of syndiotactic polystyrene (s‐PS) in melt‐crystallized samples is altered by blending with poly (2,6‐dimethyl‐1,4‐diphenylene oxide) (PPO). In particular, to render the beta form in these blends, starting with samples containing the α or γ froms, requir
Four crystal types (a, b, g, d) and some mesophases/sub-modi®cations have been identi®ed and discussed in syndiotactic polystyrene (sPS). The a-and b-forms are the main crystal packing forms in thermally-processed sPS, while the g-and d-crystals are identi®ed only in solvent-treated sPS. In addition