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Poly(methacrylates) with different kinds of dendritic moieties as side groups

✍ Scribed by Yong-Ming Chen; Chuan-Fu Chen; Wei-Hong Liu; Yu-Fei Li; Fu Xi

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 294 KB
Volume: 17
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.1996.030170606

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Alkyl methacrylate monomers with three kinds of dendritic fragments as alkyl groups, two kinds of Fréchet‐type and a new type with 3,5‐diphenoxybenzyl as first generation, were prepared by reaction of the corresponding dendritic bromides with methacrylic acid in good yield and were homopolymerized with a radical initiator. Polymers with side groups in first generation had a degree of polymerization (P̄~n~) of 17–24, markedly higher than those with side groups in second generation, P̄~n~ ≈ 6–7.

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