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Polymers having stable radicals. I. Synthesis of nitroxyl polymers from 4-methacryloyl derivatives of 2,2,6,6-tetramethylpiperidine

✍ Scribed by Kurosaki, Toshikazu ;Lee, Kyu Wan ;Okawara, Makoto


Book ID
104536650
Publisher
Wiley (John Wiley & Sons)
Year
1972
Tongue
English
Weight
712 KB
Volume
10
Category
Article
ISSN
0449-296X

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✍ Eri Yoshida; Atsutoshi Sugita πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 217 KB πŸ‘ 2 views

Synthesis of poly(styrene-b-tetrahydrofuran (THF)-b-styrene) triblock copolymers was performed by transformation from living cationic into living radical polymerization, using 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (4-hydroxy-TEMPO) as a transforming agent. Sodium 4-oxy-TEMPO, derived from 4