Substituted aromatic compounds incorporated-cardanol-formaldehyde novolac resins were synthesized by acid base catalyzed reactions. A number of improved high temperature stable interpenetrating polymer networks (semi-IPNs) were prepared by condensing novolac resins and polyurethanes prepared from ca
Polymers from renewable resources. XX. Synthesis, structure, and thermal properties of semi-interpenetrating polymer networks based on cardanol–formaldehyde-substituted aromatic compounds copolymerized resins and castor oil polyurethanes
✍ Scribed by D. K. Mohapatra; D. Das; P. L. Nayak; S. Lenka
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 156 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
A large number of improved high-temperature stable semi-interpenetrating polymer networks (semi-IPNs) were synthesized by condensing copolymerized resins with castor oil-based polyurethane using ethylene glycol dimethacrylate (EGDM) as a crosslinker. The structures of these semi-IPNs were studied using various characterization techniques such as IR and nuclear magnetic resonance (NMR) spectra, and the thermal behavior of the semi-IPNs was also studied by thermogravimetric analysis (TGA). A plausible degradation mechanism was suggested in our previous communication.
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A number of polyurethanes were synthesized by reacting castor oil with hexamethylene diisocyanate, varying the NCO/OH ratio. The polyurethanes were reacted with 2-hydroxyethyl methacrylate (HEMA) to prepare the interpenetrating polymer networks (IPNs) using benzoyl peroxide as the initiator and ethy