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Polymers from renewable resources: sorption of Cu2+ ions by cellulose graft copolymers

✍ Scribed by Ghanshyam S Chauhan; Swati Mahajan; Lalit K Guleria


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
254 KB
Volume
130
Category
Article
ISSN
0011-9164

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✦ Synopsis


To investigate the potential of some cellulose graft copolymers, especially with respect to the structural aspects of graft copolymer chains as new membrane materials, sorption studies of Cu ÷2 ions from aqueous solution ofCuSO 4 have been studied. Grafting improves metal ion sorption behaviour of cellulose. A method of synthesis for grafting copolymers has a tremendous effect on sorption behaviour. For identical graft levels graft copolymers synthesized by gamma radiation initiation sorb three times more ions as compared to the graft copolymers initially synthesized with the persulphate redox system. Copolymers having binary monomer units grafted sorb less than those which have only poly (Sty) grafted. Some reasons have been put forth to account for the sorption behaviour of graft copolymers.


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## Abstract In an attempt to develop an alternative to petro‐based polymers, we graft‐copolymerized cellulose isolated from the needles of __Pinus roxburghii__ with styrene in a limited aqueous medium in air by simultaneous irradiation using gamma rays as the initiator. The optimum conditions for o