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Polymerizations of hexamethylcyclosiloxane catalyzed by metal sulfonate/acid chloride combinations

✍ Scribed by Hicham Qayouh; Mohammed Lahcini; Jean-Luc Six; Hans R. Kricheldorf

Book ID: 102741121
Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 849 KB
Volume: 124
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.35237

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## Abstract Highly active CaCl~2~‐modified Zn‐Co(III) DMCs were prepared. XRD results showed that the modified catalyst Ca‐DMC containing 0.14 wt.‐% CaCl~2~ was amorphous. A higher polymer yield (>61 kg polymer/g catalyst) and a shorter induction period for ROP of PO were observed for Ca‐DMC than f