Polymerization of vinylchloride in the presence of Ziegler type catalysts
β Scribed by G.A. Razuvayev; K.S. Minsker; A.I. Grayevskii; Z.S. Smolyan; G.T. Fedoseyeva; D.N. Bort
- Book ID
- 118356781
- Publisher
- Elsevier Science
- Year
- 1964
- Weight
- 295 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0032-3950
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## Abstract A study has been made of the polymerization of acetylene, propyne, and butyneβ1 using aluminum triisobutyl, __n__βbutyllithium, or zinc diethyl in combination with titanium tetrachloride as catalyst. Optimum conditions for polymerization were determined by varying the catalyst compositi
Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit several features which differentiate them from polymerization reactions of β£-olefins: a relatively low ethylene reactivity, higher polymerization rates in the presence of β£-olefins, a high reaction order with respect to ethy