Polymerization of vinyl chloride by the AlEt3/benzoyl-peroxide/Lewis-base system and the role of the Lewis base in initiation
โ Scribed by E.B. Milovskaya; E.L. Kopp; O.S. Mikhailicheva; V.M. Denisov; A.I. Koltsov
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 823 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0032-3861
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## Abstract The radical polymerization behavior of vinyl monomers, such as styrene, methyl methacrylate (MMA), and vinyl acetate (VAc), in the presence of carbon black initiated by benzoyl peroxide (BPO) and 2,2'โazobisisobutyronitrile (AIBN) in ionic liquid (IL) was compared with those in toluene.
Several kinds of MgC12-supported half titanocene (XTiCl~; X = cyclopentadienyl, pentamethylcyclopentadienyl, indenyl, and heptamethylindenyl) catalysts were prepared and applied to propene polymerization using Al(i-Bu)~as cocatalyst. It was confirmed from the catalyst analysis that the ligand (X) is