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Polymerization of spiro-orthoesters—2. A kinetic approach

✍ Scribed by B. Trathnigg; G. Hippmann

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
145 KB
Volume
17
Category
Article
ISSN
0014-3057

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✦ Synopsis

The polymerization behaviour of a typical spiro-orthoester, 2-Phenoxymethyl-l,4,6-trioxa-spirol4,4)-nonane, was investigated. The polymerization rate decreases abnormally with conversion; the effect is explained by a mechanism involving deactivation of the active centres by the polymer.

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