𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Polymerization of rac -Lactide Using Schiff Base Aluminum Catalysts: Structure, Activity, and Stereoselectivity

✍ Scribed by Du, Hongzhi; Pang, Xuan; Yu, Haiyang; Zhuang, Xiuli; Chen, Xuesi; Cui, Dongmei; Wang, Xianhong; Jing, Xiabin

Book ID
118152021
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
278 KB
Volume
40
Category
Article
ISSN
0024-9297

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Enolic Schiff Base Aluminum Complexes an
Enolic Schiff Base Aluminum Complexes and Their Catalytic Stereoselective Polymerization of Racemic Lactide
✍ Xuan Pang; Hongzhi Du; Xuesi Chen; Xianhong Wang; Xiabin Jing πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 412 KB

## Abstract A series of enolic Schiff base aluminum(III) complexes LAlR (where L=NNOO‐tetradentate enolic Schiff base ligand) containing ligands that differ in their steric and electronic properties were synthesized. Their single crystals showed that these complexes are five‐coordinated around the

Stereoselective ring-opening polymerizat
Stereoselective ring-opening polymerization of rac-lactide with a single-site, racemic aluminum alkoxide catalyst: Synthesis of stereoblock poly(lactic acid)
✍ Tina M. Ovitt; Geoffrey W. Coates πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 160 KB πŸ‘ 1 views

The polymerization of racemic lactide with a racemic aluminum alkoxide catalyst is reported. Microstructural analysis of the polymer produced with 1 H NMR spectroscopy revealed that an isotactic stereoblock poly(lactic acid) formed, where each enantiomerically pure block contained an average of 11 l