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Polymerization of propylene in the presence of a VOCl3-diethylaluminium chloride complex catalyst

✍ Scribed by I.L. Dubnikova; I.N. Meshkova; Ye.I. Vizen; N.M. Chirkov

Book ID
118360253
Publisher
Elsevier Science
Year
1973
Weight
661 KB
Volume
15
Category
Article
ISSN
0032-3950

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Studies of Ziegler-type catalysts for the polymerization of ethylene and propylene II The polymerization of ethylene with VOCl3-Et3Al2Cl3 (chlorinated activator) catalysts
✍ E.W. Duck; D. Grant; J.R. Horder; D.K. Jenkins; A.E. Marlow; S.R. Wallis; A.G. D 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 626 KB

VOCla-Et3A12Cl 3 (chlorinated activator) catalysts have been employed for the polymerization of ethylene at T between 15 and 85 ° in n-hexane. Using butylperchlorocrotonate as the activator, the following catalyst efficiencies (g polymer/gV, hr, atmosphere ethylene in the cap gas) were achieved: l06