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Polymerization of phenylacetylene induced by u.v. irradiation of group 6 transition metal carbonyls

โœ Scribed by Toshio Masuda; Kaoru Yamamoto; Toshinobu Higashimura


Book ID
103352033
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
412 KB
Volume
23
Category
Article
ISSN
0032-3861

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The products generated by heating 5,6-dimethylidene-7-oxabicyclo[2.2.l]hept-2-ene (1) with Fe,(CO),, Ru,(CO),,, Os,(CO),,, Cr(CO),(MeCN),, or W(CO),(MeCN) or by treatment with Fe-atoms have been characterized by spectroscopic methods. Apart from the expected r2and y4-complexes of the triene 1, conde