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Polymerization of olefins through heterogeneous catalysis. XV. The influence of pressure in the solution copolymerization of ethylene

✍ Scribed by Isam A. Jaber; W. Harmon Ray


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
796 KB
Volume
50
Category
Article
ISSN
0021-8995

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The copolymerization of ethylene with highly active TiC14/ MgC12-supported catalysts in solution reactors at 185Β°C and 400 Psig pressure is presented. The performance of these highly active supported catalysts at high reaction temperature is characterized by a high initial rate that decays rapidly w

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## Abstract Copolymers based on ethylene with different incorporations of 1‐hexene, 1‐octene and 1‐decene were obtained. There is not any marked variation of activity when different metallocenes were tested. The type and the concentration of the comonomer in the feed do not have a strong influence