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Polymerization of N-phenylmaleimide with rare earth coordination catalysts

✍ Scribed by Liming Jiang; Yifeng Zhang; Zhiquan Shen; Lianfang Shen; Hanzhen Yuan

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 216 KB
Volume: 17
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.1996.030170609

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✦ Synopsis

Abstract

A highly active rare earth coordination catalyst composed of neodymium acetylacetonate, dibutylmagnesium, and hexamethylphosphoramide (mole ratio 1:7:14) for the polymerization of N‐phenylmaleimide (N‐PMI) was developed. The resulting poly(N‐PMI) has high molecular weight (M̄~n~ = 9.0 × 10^4^) and shows excellent thermal stability.

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