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Polymerization of methyl methacrylate with malononitrile and Fe(III) mixture

✍ Scribed by Dass, N. N. ;Begum, S. S.

Book ID
105335951
Publisher
John Wiley and Sons
Year
1985
Weight
186 KB
Volume
23
Category
Article
ISSN
0360-6376

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Mechanism of polymerization of methyl me
Mechanism of polymerization of methyl methacrylate by triphenylphosphine and Fe(III) complex in dimethyl sulphoxide
✍ A. Dutta; P.K. Mahato; N.N. Dass πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 336 KB

The triphenylphosphine (TPP) initiated polymerization of methyl methacrylate (MMA) in dimethyl sulphoxide (DMSO) has been studied. The polymerization was found to be solvent-sensitive and could be accelerated by Lewis acids like Fe 3Γ· . Kinetic studies showed that the propagation was free radical in