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Polymerization of methyl methacrylate by sterically modulated bis(salicylaldiminate)-cobalt(II) complexes combined with methylaluminoxane

โœ Scribed by Bijal Kottukkal Bahuleyan; Deepak Chandran; Chang Hun Kwak; Chang-Sik Ha; Il Kim


Book ID
105735711
Publisher
The Polymer Society of Korea
Year
2008
Tongue
English
Weight
211 KB
Volume
16
Category
Article
ISSN
1598-5032

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The one-pot reactions of salicylaldehyde or its derivatives with 2,6-dialkyl substituted anilines in the presence of metallating agent, Co(OAc) 2 .4H 2 O, yield a series of cobalt(II) complex precatalysts (Ar 1 -N C-Ar 2 -O) 2 Co (1, Ar 1 = 2,6-dimethylaryl, Ar 2 = aryl; 2, Ar 1 = 2,6diethylaryl, Ar