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Polymerization of mesomorphic monomers. I. Bulk polymerization of cholesteryl methacrylate

✍ Scribed by Tanaka, Yoshio ;Kabaya, Sanae ;Shimura, Yukio ;Okada, Akira ;Kurihara, Yoshie ;Sakakibara, Yoshiaki


Publisher
Wiley (John Wiley & Sons)
Year
1972
Tongue
English
Weight
182 KB
Volume
10
Category
Article
ISSN
0449-2986

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Bulk polymerization of cholesteryl acryl
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Thermal bulk polymerization of cholester
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## Abstract The thermal bulk polymerization of cholesteryl acrylate was carried out in the solid phase, the mesomorphic phase, and the liquid phase to study the effect of monomer ordering on polymerization rate and polymer properties. The rate increased with decreasing ordering (or enhanced mobilit

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The bulk polymerization of 2-allylphenylscrylic ester and of 2-allylphenylmethacrylic ester at 60-80Β°C. was studied. It was observed that under these conditions azobisisobutyronitrile, lauroyl peroxide, and benzoyl peroxide have satisfactory activity as initiators. The influence of atmospheric oxyge