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Polymerization of isoprene and styrene in the interlayer spacing of graphite

โœ Scribed by H. Shioyama

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
235 KB
Volume
35
Category
Article
ISSN
0008-6223

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Calculations are made of the effect of the zero point lattice vibrations in the out-of-plane mode on the interlayer spacing and the C,, elastic constant of a graphite crystal. It is found that these vibrations expand the lattice by about 0.5% and contribute 0.24 x 10" dynes/cm' to C,,.

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Studies of the average interlayer spacing. &,, strain parameter, e, and fractional weight changes, Aw/~, were made of a pitch coke heat treated at tem~mtures in the range 1250,230OT for periods up to 25 h in inert atmosphere. Application of the superposition technique lo the change in d,")? gave an